It is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic stainless steel. A comparative study of localized corrosion and stress. Also lessons learned and special recommendations are included. In addition, transgranular stress corrosion cracking of 304l stainless steel pipe clamps in direct use geothermal water heating applications. Fitzpatrick plant licensee event report 87003 identifies broken bolts from the high pressure coolant injection hpci terry turbine throttle valve lifting beam. Introduction a stress corrosion cracking scc evaluation of nitinol 60 was performed because this alloy is considered a candidate bearing material for. If something prevented oxygen from getting to the spot, it might have caused the rust, as stainless is susceptible to rust in anoxic salt environments, as the chlorine strips away the protective. These steels belong to martensitic stainless crsteel grades and meet ambitious requirements in terms of strength, hardness. Masami mayuzumi, taku arai and koichiro hide central research institute of electric power industry chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of 35%. Pitting or crevice corrosion can occur on most stainless steel grades. Corrosion resistance of high nitrogen steels 57 fig. Corrosion resistance of high nitrogen steels intechopen. It contains data on physical, elastic, mechanical, optical and thermal properties and specific data for use in space conditions. Since its development in the early 1990s, cronidur 30 x30crmo 151 plus 0.
Astm 304 and 316 austenitic steels have limited resistance to stress corrosion. Overaging to the h condition provides a superior combination of strength, toughness and stress corrosion cracking resistance compared with 455 or 8 stainless. Prevention of white etching cracks in rolling bearings. Irradiationinduced stress corrosion cracking of austenitic stainless steels. Cronidur 30 is a martensitic through hardened steel that, because of its alloy composition carbon, nitrogen, chromium and molybdenum exhibits exceptional corrosion resistance, strength. Stress corrosion cracking scc is characterized by cracks propagating either.
Conditions necessary for stress corrosion cracking 7. Chloride stress corrosion cracking inspectioneering. Stress corrosion cracking scc can slowly destroy your brewery equipment without warning. In the power production plants, the alloy is used in superheater and reheater tubes. Dependence of average channel height on a dislocation loop density b void density for. Transgranular stress corrosion cracking of 304l stainless. Worth mentioning for c276 is also the exceptional resistance to corrosive media under oxidizing and reducing conditions.
Corrosion developed after 4 weeks in the 304 and 304l specimens, and after 32 weeks in the 316l specimen. Integral to johns manville thermo1200 and to sproule wr1200 is xox corrosion inhibitor, a distinctive formula and process that inhibits corrosion to the outside surfaces of pipe and equipment, especially stress corrosion cracking. Apart from applications in furnace construction, chemical processing, pollution control and power generation, there is a variety of further purposes, i. Inhibition of stress corrosion cracking in 304 stainless steel through. Intergranular stress corrosion cracking igscc of type 304 stainless steel has been a major concern in boiling water reactors undergoing normal water containing 100 to 300 ppb of oxygen, 200 to 500 ppb of h 2 o 2 and corrosion evaluation of austenitic stainless steel type 304 in acid. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. Scanning electron micrographs of stress corrosion cracks in type 304 ss tested in 0. Your tanks are the core of your brewery, so it is important to understand what scc is, what causes it, and what to do when your tanks suffer from this type of damage. It is generally not well understood, and can, given the right conditions, cause catastrophic failure. Chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless. Ig and tg in sheet specimens of stainless steels and tg in tube specimens as shown in figs. This suggests that the alloy composition plays a role in stress corrosion cracking susceptibility.
Available in various forms such as bars, tubes, pipes, rods, flanges, fittings, structural shapes, plates and sheets. Stress corrosion cracking scc of duplex stainless steel. Atmospheric stress corrosion cracking susceptibility. A corrosive medium especially chloridebearing or hydrogensulphide h 2s media. Stress corrosion cracking from a piece of grit is a good candidate. Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic environment. Stress corrosion cracking scc results from the combined action of three factors. The alloys 304, 304l, and 304h are the most susceptible of the austenitic stainless steels to stress corrosion cracking scc in halides because of their relatively low nickel content. Hence, in current study the susceptibility to stress corrosion cracking of two high strength steels, namely cronidur 30 and aisi440c was investigated. Corrosion behaviour of stainless steel 304 electroplated. Iaea nuclear energy series technical reports stress corrosion cracking in light water reactors. The austenitic stainless steel 6mo was developed on basis of alloy 904l 1. Slow strain rate tests ssrts were conducted on 304 steel. Consequently, there has never been a known case of wec with cronidur 30 bearings.
Behaviour of cronidur30 and 440c steels under different scc. Stress corrosion cracking in a brewery paul mueller company. Despite the fact that this alloy has been designated as having a high resistance to stress corrosion cracking when in the t6 or t8 condition, it can, if incorrectly worked or heat treated, have an increased susceptibility to all types of corrosion see nasa msfc spec 522a and esa pss01736. In recent years, failures of reactor internal components have been observed after the components have reached neutron fluence levels 5 x 10 20 ncm2 e 1 mev. Stress corrosion cracking scc is a phenomenon experienced from time to time in stainless steels. Normally 50 deg c but can occur at lower temperatures around 25 deg c in specific environments, notably swimming pools. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. Behaviour of cronidur30 and 440c steels under different. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Cracking was mainly transgranular with sections of intergranular branching.
The effects of titanium ion implantation on the stress corrosion cracking scc. The general pattern of the observed failures indicates that as nuclear plants age and fluence increases, various apparently nonsensitized austenitic. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization. Schematic design of a pressure electro slag remelting furnace pesr. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Stocking distributor of metal alloys including stainless steel 155 alloys. The effects of dissolved oxygen content in the water, heat treatment, especially slight sensitization, and most importantly chloride ion concentration on the susceptibility of type 304 stainless steel to stress corrosion cracking scc were investigated. I would like to know about the possibilities of stress corrosion cracking for ss 304l at following thermal hydraulic conditions. This new second edition serves as a goto reference on the complex subject of stress corrosion cracking scc, offering information to help metallurgists, materials scientists, and designers determine whether scc will be an issue for their design or application. Incoloy 800 is used in the chemical plants for components of heat exchangers and transmission pipes of nitric acid solutions that need to prevent attack of chloride stress corrosion cracking. The physical fundamentals of nitrogen pick up are specified over the sievert square root law, accordingly that the nitrogen solubility is.
These steels belong to martensitic stainless crsteel grades and meet ambitious requirements in terms of strength, hardness, wear and corrosion resistance. However, the molybdenum content at 6mo was raised to 6. R specimen show ing transgranular and intergranular stress corrosion cracking. The corrosion properties of spacelab structural alloy. The bolts of type 410 stainless steel with hardness in the upper rc30 range failed from intergranular stress corrosion cracking.
Cronidur 30 steel stressstrain curves and tensile data for asreceived. Excellent resistance to scc stress corrosion cracking in sour and chloride environments. An accurate evaluation of stress corrosion cracking scc in cr. Ricker, national institute of standards and technology stress corrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Materials and processes for use in space on launchers, satellites, payloads. Stress corrosion cracking in carbon steel bigpond, cracks seen are scc in carbon steel intergranular cracks along grain boundaries will come in welds hazparent plate where hardness is high or varied from other locations. Chloride stress corrosion cracking in austentic hse. The original 1997 cepa stress corrosion cracking recommended practices hereafter referred to as the practices were prepared and made public by cepa in response to a the national energy board of canadas public inquiry mh295 into the problem of stress corrosion cracking scc in oil and gas pipelines. Chloride induced stress corrosion cracking of type 304 and. Pitting corrosion has been reported from household bleach spills on stainless steel 304 type sinks in domestic environments. Good practices and lessons learned international atomic energy agency vienna isbn 978920. Stress corrosion cracking of type 304 stainless steel with. There is an additional risk of stress corrosion cracking scc at. Stress corrosion cracking facts and how to reduce the risk.
9 208 1468 1526 970 1319 404 24 842 880 646 970 207 1306 477 1499 383 48 559 1043 268 1436 166 170 982 229 285 1274 1523 1486 1147 130 1242 506 100 556 404 1153 1398 966 62